Editor: Claudio Santi

Organoselenium Chemistry: Between Synthesis and Biochemistry

eBook: US $89 Special Offer (PDF + Printed Copy): US $184
Printed Copy: US $140
Library License: US $356
ISBN: 978-1-60805-839-6 (Print)
ISBN: 978-1-60805-838-9 (Online)
Year of Publication: 2014
DOI: 10.2174/97816080583891140101

Introduction

The use of organoselenium reagents as catalysts is a common thread that runs through the chapters of this book, introducing important aspects of the modern organoselenium chemistry: organocatalysis, green chemistry, bioinspiration, antioxidant activity. The eBook covers the most recent developments in the classical synthetic application of organoselenium reagents such as electrophilic, nucleophilic and free radical reagents. The volume also features a discussion on the synthesis and the synthetic applications of some emerging classes of selenium compounds such as hypervalent selenium species and selenoamides, and also addresses some biological aspects such as the antimicrobial activity of organoselenium derivatives and the biochemistry of selenoproteins. A number of eminent scientists from different research groups were involved in the preparation of the 13 chapters of the book, making Organoselenium Chemistry: Between Synthesis and Biochemistry an excellent reference about selenium chemistry for researchers and graduate students in the field of selenium chemistry.

Indexed in: Book Citation Index, Science Edition, EBSCO.

Foreword

- Pp. i
Thomas Wirth
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Preface

- Pp. ii-iii (2)
Claudio Santi
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List of Contributors

- Pp. iv-vi (3)
Claudio Santi
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Introduction

- Pp. 3-7 (5)
Claudio Santi
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Electrophilic Selenium Reagents: Addition Reactions to Double Bonds and Selenocyclizations

- Pp. 8-60 (53)
Jacek Ścianowski, Zbigniew Rafiński
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Nucleophilic Selenium: Nucleophilic Substitution

- Pp. 61-93 (33)
Barahman Movassagh, Mozhgan Navidi
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Organoselenium Compounds as Precursor of Radicals

- Pp. 94-119 (26)
Jarosław Lewkowski
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Hypervalent Selenium Derivatives

- Pp. 120-145 (26)
Józef Drabowicz, Piotr Kiełbasiński, Adrian Zając, Patrycja Pokora-Sobczak
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Selenoamides, Synthetic Methods and Recent Progress on their Synthetic Applications

- Pp. 146-165 (20)
Toshiaki Murai
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Enantioselective Catalysis for the Preparation of Organoselenium Compounds and Applications

- Pp. 166-196 (31)
Francesca Marini, Luana Bagnoli, Silvia Sternativo
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Eco-Friendly Access and Application of Organoselenium Reagents: Advances Toward Green Chemistry

- Pp. 197-267 (71)
Antonio L. Braga, Ricardo S. Schwab, Oscar E.D. Rodrigues
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Biochemistry and Nutrition of Selenium: From Inorganic Forms to Endogenous Proteins

- Pp. 268-327 (60)
Bartolini Desirèe, Ciffolilli Silvia, Piroddi Marta, Murdolo Giuseppe, Tortoioli Cristina, Francesco Galli
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Antimicrobial Activity of Organoselenium Compounds

- Pp. 328-344 (17)
Donatella Pietrella
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Selenium and “Bio-Logic” Catalysis: New Bioinspired Catalytic Reactions

- Pp. 345-360 (16)
Caterina Tidei, Claudio Santi
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Antioxidant Organoselenium Molecules

- Pp. 361-378 (18)
Michio Iwaoka
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<sup>77</sup>Se NMR: Theoretical Aspects and Practical Applications

- Pp. 379-415 (37)
Waro Nakanishi, Satoko Hayashi
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Index

- Pp. 418-431 (14)
Claudio Santi
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