Advances in Organic Synthesis

Volume 5

by

Atta-ur-Rahman

DOI: 10.2174/97816080548001130501
eISBN: 978-1-60805-480-0, 2013
ISBN: 978-1-60805-618-7
ISSN: 1574-0870 (Print)
ISSN: 2212-408X (Online)



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Advances in Organic Synthesis is a book series devoted to the latest advances in synthetic approaches towards challen...[view complete introduction]
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Table of Contents

Preface

- Pp. i- (1)
Atta-ur-Rahman
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List of Contributors

- Pp. ii-iv (3)
Atta-ur-Rahman
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Solid-Supported Synthesis of Glycoconjugates

- Pp. 3-50 (48)
Harri Lönnberg

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Chiral Molecular Receptors Based on Trans-Cyclohexane-1,2- Diamine

- Pp. 51-100 (50)
Ignacio Alfonso

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Regio- and Stereoselective Ring Opening of Allylic Epoxides

- Pp. 101-184 (84)
Mauro Pineschi, Ferruccio Bertolini, Valeria Di Bussolo and Paolo Crotti

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Conjugated Dendrimers with Poly(Phenylenevinylene) and Poly(Phenyleneethynylene) Scaffolds

- Pp. 185-234 (50)
Joaquín C. García-Martínez, Enrique Díez-Barra and Julián Rodríguez-López

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α-Activated Cross Conjugated Cycloalkenone Systems in Organic Synthesis

- Pp. 235-278 (44)
Yen-Ku Wu, Tai Wei Ly and Kak-Shan Shia

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An Update on Trifluoromethylation of Carbonyl Compounds

- Pp. 279-308 (30)
Nubia Boechat and Monica Macedo Bastos

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Synthetic Chemistry with N-Acyliminium Ions derived from Piperazine-2,5-diones and Related Compounds

- Pp. 309-354 (46)
Carmen Avendaño and Elena de la Cuesta

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Advances in the Synthesis of Organometallic Amino Acids and Analogues

- Pp. 355-378 (24)
Poulami Jana, Sibaprasad Maity and Debasish Haldar

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Index

- Pp. 379-397 (19)
Atta-ur-Rahman
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Preface

This eBook should be of interest to students and researchers interested in the art of organic synthesis. The chapters describe how challenging molecules have been synthesised by experts in the field and how new methodologies have been developed and applied where conventional chemistry had failed.

In the first article, Lönnberg describes the synthesis of glycoconjugates by the strong binding of carbohydrates with protein receptors. In another review, Alfonso highlights the development of chiral molecular receptors based on enantiopure trans-cyclohexane-1,2-diamine. In an interesting contribution, Pineschi and coworkers review the selective opening of asymmetric ring to allylic epoxides with nucleophiles of different kinds. Next, García-Martínez and colleagues focus on the main strategies for the synthesis of poly(phenylenevinylene)- and poly(phenyleneethynylene)-based dendrimers as well as approaches to hybrid dendritic structures that combine both scaffolds. In another review, Wu et al. have reviewed organic synthesis of a-activated cross conjugated cycloalkenone systems. Boechat and Bastos provide updates on the synthetic methods developed for the direct introduction of a trifluoromethyl group in carbonyl compounds. Avendaño and Cuesta discuss synthetic chemistry with n-acyliminium ions derived from piperazine-2,5-diones and related compounds. In the last chapter of this eBook, Jana and her coworkers review advancements related to the synthesis of organometallic amino acids and analogues.

I am thankful for the time and efforts made by the editorial personnel at Bentham Science Publishers, Mr. Mahmood Alam, Taimur A. Khan and Ms. Sarah A. Khan.

Atta-ur-Rahman, FRS
Kings College
University of Cambridge
Cambridge
UK

List of Contributors

Editor(s):
Atta-ur-Rahman
University of Cambridge
UK




Contributor(s):
Harri Lönnberg
Department of Chemistry
University of Turku
Turku, FIN -20014
Finland


Ignacio Alfonso
Departamento de Química Biológica y Modelización Molecular
Instituto de Química Avanzada de Cataluña
Consejo Superior de Investigaciones Científicas
IQAC -CSIC, Jordi Girona
18 -26
Barcelona, E -08034
Spain


Mauro Pineschi
Dipartimento di Farmacia
Università di Pisa
Via Bonanno 33
Pisa, 56126
Italy


Ferruccio Bertolini
Dipartimento di Farmacia
Università di Pisa
Via Bonanno 33
Pisa, 56126
Italy


Valeria Di Bussolo
Dipartimento di Farmacia
Università di Pisa
Via Bonanno 33
Pisa, 56126
Italy


Paolo Crotti
Dipartimento di Farmacia
Università di Pisa
Via Bonanno 33
Pisa, 56126
Italy


Joaquín C. García -Martínez
Facultad de Farmacia
Universidad de Castilla -La Mancha
Avda. de los Estudiantes s/n
Albacete, 02071
Spain


Enrique Díez –Barra
Facultad de Ciencias y Tecnologías Químicas
Universidad de Castilla -La Mancha
Avda. Camilo José Cela, 10
Ciudad Real, 13071
Spain


Julián Rodríguez -López
Facultad de Ciencias y Tecnologías Químicas
Universidad de Castilla -La Mancha
Avda. Camilo José Cela, 10
Ciudad Real, 13071
Spain


Yen -Ku Wu
Department of Chemistry
National Tsing Hua University
Hsinchu, 30013
R.O.C. Taiwan


Tai Wei Ly
Axikin Pharmaceuticals
Inc.,10835 Road to the Cure
Suite 250
San Diego
California, 92121
USA


Kak -Shan Shia
Institute of Biotechnology and Pharmaceutical Research
National Health Research Institutes
Miaoli County, 35053
R.O.C. Taiwan


Nubia Boechat
Fundação Oswaldo Cruz
Farmanguinhos, Rua Sizenando Nabuco
100 CEP 21041 -250
Manguinhos - Rio de Janeiro
RJ
Brazil


Monica Macedo Bastos
Fundação Oswaldo Cruz
Farmanguinhos, Rua Sizenando Nabuco
100 CEP 21041 -250
Manguinhos - Rio de Janeiro
RJ
Brazil


Carmen Avendaño
Departamento de Química Orgánica y Farmacéutica
Facultad de Farmacia
Universidad Complutense
Madrid, 28040
Spain


Elena de la Cuesta
Departamento de Química Orgánica y Farmacéutica
Facultad de Farmacia
Universidad Complutense
Madrid, 28040
Spain


Poulami Jana
Department of Chemical Sciences
Indian Institute of Science Education and Research
Kolkata, Mohanpur
West Bengal, 741252
India


Sibaprasad Maity
Department of Chemical Sciences
Indian Institute of Science Education and Research
Kolkata, Mohanpur
West Bengal, 741252
India


Debasish Haldar
Department of Chemical Sciences
Indian Institute of Science Education and Research
Kolkata, Mohanpur
West Bengal, 741252
India




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